Little secret.
For long exposure photography in a tripod, is better! :-P
Joking aside (especially that is not true if we consider the 1/200sec like long exposure , see other topic)
You can make excellent long poses, just after the sunset time. I'm not an early bird, but I guess it works well.
At that time the day you can take pictures without filters which is a big advantage, you used all the quality of your couple, camera / lens. Another advantage is you do not have to buy a filter and you do not need to know counted, which can help to make his first long exposure, with a great quality and without investing anything!
So go to it!